Thanks for posting and sharing your feedback!
We do not currently support Chip & PIN for the Payoneer card, however this is something that we are working on for the future. If anyone else is interested in having this support for their Payoneer card, please post and share your feedback with us.
In regards to our mobile app, we're currently working on the next major version release and have a lot of new and exciting features in the works. PayPass is not currently one of them, but I'll certainly pass your suggestion on to our mobile app dev team.
Nissim | Head of Community at Payoneer | www.payoneer.com